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Glacial influence on the geochemistry of riverine iron fluxes to the Gulf of Alaska and effects of deglaciation ArchiMer
Schroth, Andrew W.; Crusius, John; Chever, Fanny; Bostick, Benjamin C.; Rouxel, Olivier.
Riverine iron (Fe) derived from glacial weathering is a critical micronutrient source to ecosystems of the Gulf of Alaska (GoA). Here we demonstrate that the source and chemical nature of riverine Fe input to the GoA could change dramatically due to the widespread watershed deglaciation that is underway. We examine Fe size partitioning, speciation, and isotopic composition in tributaries of the Copper River which exemplify a long-term GoA watershed evolution from one strongly influenced by glacial weathering to a boreal-forested watershed. Iron fluxes from glacierized tributaries bear high suspended sediment and colloidal Fe loads of mixed valence silicate species, with low concentrations of dissolved Fe and dissolved organic carbon (DOC). Iron isotopic...
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Ano: 2011 URL: http://archimer.ifremer.fr/doc/00044/15483/12872.pdf
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