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	Provedor de dados ArchiMer (1) Autor Coelho, Cristina (1) David, Adelina (1) Huang, Jing (1) Le Gac, Pierre Yves (1) Lorthioir, Cedric (1) Richaud, Emmanuel (1) Mais... Palavra-chave Crosslinking (1) Kinetic modeling (1) Polydicyclopentadiene (1) Thermal oxidation (1) Tipo do documento Text (1) Ano 2019 (1) País France (1) Idioma Inglês (1)		Ordenar por:  Relevância Autor Título Ano Registros recuperados: 1 Primeira ... 1 ... Última Thermal oxidation of Poly(dicyclopentadiene)– kinetic modeling of double bond consumption ArchiMer Huang, Jing; David, Adelina; Le Gac, Pierre Yves; Lorthioir, Cedric; Coelho, Cristina; Richaud, Emmanuel. This paper reports chemical changes that occur in polydicyclopentadiene during thermal oxidation at several temperatures and oxygen pressures. A particular attention was paid to the double bond consumption since these latter are associated with crosslinking and subsequent changes in mechanical properties. A kinetic model was derived from the experimental results. Its rate constants were assessed from the “inverse approach” based on their selective identification under specific ageing conditions (for example under oxygen excess). The resulting model satisfactorily describes both carbonyl formation and double bond consumption for a wide range of temperature and oxygen pressure for the first time. This can be exploited to predict the changes of local... Tipo: Text Palavras-chave: Polydicyclopentadiene; Thermal oxidation; Kinetic modeling; Crosslinking. Ano: 2019 URL: https://archimer.ifremer.fr/doc/00502/61327/64899.pdf Registros recuperados: 1 Primeira ... 1 ... Última

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