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Nonuniform ocean acidification and attenuation of the ocean carbon sink ArchiMer
Fassbender, Andrea J.; Sabine, Christopher L.; Palevsky, Hilary I..
Surface ocean carbon chemistry is changing rapidly. Partial pressures of carbon dioxide gas (pCO(2)) are rising, pH levels are declining, and the ocean's buffer capacity is eroding. Regional differences in short-term pH trends primarily have been attributed to physical and biological processes; however, heterogeneous seawater carbonate chemistry may also be playing an important role. Here we use Surface Ocean CO2 Atlas Version 4 data to develop 12month gridded climatologies of carbonate system variables and explore the coherent spatial patterns of ocean acidification and attenuation in the ocean carbon sink caused by rising atmospheric pCO(2). High-latitude regions exhibit the highest pH and buffer capacity sensitivities to pCO(2) increases, while the...
Tipo: Text Palavras-chave: Ocean acidification; Carbon sink; Revelle factor; Carbon cycle.
Ano: 2017 URL: https://archimer.ifremer.fr/doc/00661/77321/78794.pdf
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Seasonal Asymmetry in the Evolution of Surface Ocean pCO(2) and pH Thermodynamic Drivers and the Influence on Sea-Air CO2 Flux ArchiMer
Fassbender, Andrea J.; Rodgers, Keith B.; Palevsky, Hilary I.; Sabine, Christopher L..
It has become clear that anthropogenic carbon invasion into the surface ocean drives changes in the seasonal cycles of carbon dioxide partial pressure (pCO(2)) and pH. However, it is not yet known whether the resulting sea-air CO2 fluxes are symmetric in their seasonal expression. Here we consider a novel application of observational constraints and modeling inferences to test the hypothesis that changes in the ocean's Revelle factor facilitate a seasonally asymmetric response in pCO(2) and the sea-air CO2 flux. We use an analytical framework that builds on observed sea surface pCO(2) variability for the modern era and incorporates transient dissolved inorganic carbon concentrations from an Earth system model. Our findings reveal asymmetric amplification...
Tipo: Text Palavras-chave: Revelle Factor; Carbon cycle; Seasonal cycle; CO2 fluxes; Ocean acidification.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00675/78679/80884.pdf
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Technical note: Interpreting pH changes ArchiMer
Fassbender, Andrea J.; Orr, James C.; Dickson, Andrew G..
he number and quality of ocean pH measurements have increased substantially over the past few decades such that trends, variability, and spatial patterns of change are now being evaluated. However, comparing pH changes across domains with different initial pH values can be misleading because a pH change reflects a relative change in the hydrogen ion concentration ([H+], expressed in mol kg−1) rather than an absolute change in [H+]. We recommend that [H+] be used in addition to pH when describing such changes and provide three examples illustrating why.
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Ano: 2021 URL: https://archimer.ifremer.fr/doc/00683/79539/82217.pdf
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