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Fry, Claudia H.; Tyrrell, Toby; Hain, Mathis P.; Bates, Nicholas R.; Achterberg, Eric P.. |
The export of calcium carbonate (CaCO3) from the surface ocean is poorly constrained. A better understanding of the magnitude and spatial distribution of this flux would improve our knowledge of the ocean carbon cycle and marine biogeochemistry. Here, we investigate controls over the spatial distribution of total alkalinity in the surface global ocean and produce a tracer for CaCO3 cycling. We took surface ocean bottle data for total alkalinity from global databases (GLODAP, CARINA, PACIFICA) and subtracted the effects of several processes: evaporation and precipitation, river discharge, and nutrient uptake and remineralization. The remaining variation in alkalinity exhibits a robust and coherent pattern including features of large amplitude and spatial... |
Tipo: Text |
Palavras-chave: Alkalinity; Calcium carbonate; Biogeochemical cycles; Tracers. |
Ano: 2015 |
URL: https://archimer.ifremer.fr/doc/00292/40367/83011.pdf |
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Wu, Yingxu; Hain, Mathis P.; Humphreys, Matthew P.; Hartman, Sue; Tyrrell, Toby. |
Previous work has not led to a clear understanding of the causes of spatial pattern in global surface ocean dissolved inorganic carbon (DIC), which generally increases polewards. Here, we revisit this question by investigating the drivers of observed latitudinal gradients in surface salinity-normalized DIC (nDIC) using the Global Ocean Data Analysis Project version 2 (GLODAPv2) database. We used the database to test three different hypotheses for the driver producing the observed increase in surface nDIC from low to high latitudes. These are (1) sea surface temperature, through its effect on the CO2 system equilibrium constants, (2) salinity-related total alkalinity (TA), and (3) high-latitude upwelling of DIC- and TA-rich deep waters. We find that... |
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Ano: 2019 |
URL: https://archimer.ifremer.fr/doc/00675/78726/80988.pdf |
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