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A method for high frequency underway N 2 fixation measurements: Flow-through incubation Acetylene Reduction Assays by Cavity ring down laser Absorption Spectroscopy (FARACAS) ArchiMer
Cassar, Nicolas; Tang, Weiyi; Gabathuler, Hans; Huang, Kuan.
Because of the difficulty in resolving the large variability of N2 fixation with current methods which rely on discrete sampling, the development of new methods for high resolution measurements is highly desirable. We present a new method for high-frequency measurements of aquatic N2 fixation by continuous flow-through incubations and spectral monitoring of the acetylene (C2H2, a substrate analog for N2) reduction to ethylene (C2H4). In this method, named “Flow-through incubation Acetylene Reduction Assays by Cavity ring-down laser Absorption Spectros-copy” (FARACAS), dissolved C2H2 is continuously admixed with seawater upstream of a continuous-flow stirred-tank reactor (CFSR) in which C2H2 reduction takes place. Downstream of the flow-through incubator,...
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Ano: 2018 URL: https://archimer.ifremer.fr/doc/00420/53139/54103.pdf
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