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Polychloroprene behaviour in a marine environment: Role of silica fillers ArchiMer
Tchalla, Siwavi Tatiana; Le Gac, Pierre-yves; Maurin, R.; Creac'Hcadec, R..
Polychloroprene rubbers are widely used in marine structures and often filled with silica in order to increase mechanical properties. The presence of silica fillers leads to a complex degradation of the material. This study aims to understand the deeper degradation mechanisms involved when a silica filled polychloroprene is used in sea water. To do so, 4 polychloroprene rubbers filled with different amounts of silica (from 0 to 45 phr) were aged in natural sea water for 6 months at temperatures ranging from 25 to 60 °C. Moreover, a natural rubber with similar formulation was also considered in order to evaluate the role of the chlorine atom in the degradation. . The chemistry and mechanics of the rubber degradation were also studied. In the presence of...
Tipo: Text Palavras-chave: Polychloroprene; Seawater; Silica filler; Hydrolysis.
Ano: 2017 URL: http://archimer.ifremer.fr/doc/00376/48689/49020.pdf
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