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| Bown, J.; Boye, M.; Laan, P.; Bowie, A. R.; Park, Y. -h.; Jeandel, C.; Nelson, D. M.. |
| Processes of cobalt (Co) entrainment from shelf sediments over the Kerguelen Plateau were studied during the KEOPS (Kerguelen Ocean Plateau compared Study) in order to explain the exceptionally high dissolved cobalt concentrations that have been measured in the surface waters above the Kerguelen Plateau, and in intermediate and deep waters above its eastern slope. Lateral advection and dissolution of Co contained in basalt sediments around Heard Island, a main source of lithogenic Co in the study area, were shown to imprint the process of surface enrichment over the plateau. Dissolved Co enrichment was strongest at the intercept of the eastern slope with intermediate and deep waters, probably due to more efficient mobilisation of the sediments in the slope... |
| Tipo: Text |
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| Ano: 2012 |
URL: http://archimer.ifremer.fr/doc/00139/25058/23163.pdf |
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| Bown, J.; Boye, Marie; Nelson, D. M.. |
| The organic speciation of dissolved cobalt (DCo) was investigated in the subtropical region of the southeastern Atlantic, and in the Southern Ocean in the Antarctic Circumpolar Current (ACC) and the northern Weddell Gyre, between 34A degrees 25A ' S and 57A degrees 33A ' S along the Greenwich Meridian during the austral summer of 2008. The organic speciation of dissolved cobalt was determined by competing ligand exchange adsorptive cathodic stripping voltammetry (CLE-AdCSV) using nioxime as a competing ligand. The concentrations of the organic ligands (L) ranged between 26 and 73 pM, and the conditional stability constants (log K'(CoL)) of the organic complexes of Co between 17.9 and 20.1. Most dissolved cobalt was organically complexed in the water-column... |
| Tipo: Text |
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| Ano: 2012 |
URL: https://archimer.ifremer.fr/doc/00266/37698/36900.pdf |
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