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Dissolved and particulate metals (Fe, Zn, Cu, Cd, Pb) in two habitats from an active hydrothermal field on the EPR at 13 degrees N ArchiMer
Sarradin, Pierre-marie; Lannuzel, D; Waeles, M; Crassous, Philippe; Le Bris, Nadine; Caprais, Jean-claude; Fouquet, Yves; Fabri, Marie-claire; Riso, R.
The distribution of Fe, Cu, Zn, Pb, Cd between the dissolved (<2 mu m) and the particulate (>2 mu m) fractions was measured after in-situ filtration in two hydrothermal habitats. The total metal concentration ranges exhibit a clear enrichment compared with the seawater concentration, accounting for the hydrothermal input for all the metals considered. Iron is the predominant metal (5-50 mu M) followed by Zn and Cu. Cd and Pb are present at the nM level. At the scale studied, the behavior of temperature, pH and dissolved iron is semi-conservative whereas the other dissolved and particulate metals are characterized by non-conservative patterns. The metal enrichment of the >2 mu m fraction results from the settlement and accumulation of particulate...
Tipo: Text Palavras-chave: Hydrothermal fauna; Habitats; Particulate; Dissolved; Metals.
Ano: 2008 URL: http://archimer.ifremer.fr/doc/2008/publication-3830.pdf
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Speciation of dissolved copper within an active hydrothermal edifice on the Lucky Strike vent field (MAR, 37 degrees N) ArchiMer
Sarradin, Pierre-marie; Waeles, M; Bernagout, Solene; Le Gall, Christian; Sarrazin, Jozee; Riso, R.
The objective of this study was to deter-mine the concentrations of different fractions of dissolved copper (after filtration at 0.45 mu m) along the cold part of the hydrothermal fluid-seawater mixing zone on the Tour Eiffel edifice (MAR). Dissolved copper was analyzed by stripping chronopotentiometry (SCP) after chromatographic C-18 extraction. Levels of total dissolved copper (0.03 to 5.15 mu M) are much higher than those reported for deep-sea oceanic waters but in accordance with data previously obtained in this area. Speciation measurements show that the hydrophobic organic fraction (C18Cu) is very low (2 +/- 1%). Dissolved copper is present mainly as inorganic and hydrophilic organic complexes (nonC(18)CU). The distribution of copper along the pH...
Tipo: Text Palavras-chave: Mid Atlantic Ridge; Hydrothermal vent; Speciation; Dissolved copper.
Ano: 2009 URL: http://archimer.ifremer.fr/doc/2009/publication-5301.pdf
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