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Roekens, E.J.; Van Grieken, R.E.. |
The rate of iron(II) oxidation in the North Sea water of pH 5.5-10 in the range 10-25°C has been studied. The oxygenation rate depends linearly on the iron(II) and dissolved oxygen concentrations. The second-order dependence on (OH<sup>-</sup>), found by several investigators for synthetic solutions, was confirmed in seawater, but only for pOH>6.9. For pOH<5.9 the rate appeared to be independent of the pOH. In the intermediate range, pOH<5.9-6.9, corresponding to the natural pH of seawater, a first-order dependence on the pOH is obeyed. The important discrepancy in the literature between the second-order rate constant for NaCHO<sub>3</sub> solutions and for seawater can be attributed predominantly to the incorrect... |
Tipo: Info:eu-repo/semantics/article |
Palavras-chave: Iron; Kinetics; Oxidation. |
Ano: 1983 |
URL: http://www.vliz.be/nl/open-marien-archief?module=ref&refid=3293 |
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