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Florisphaera profunda and the origin and diagenesis of carbonate phases in eastern Mediterranean sapropel units ArchiMer
Thomson, J; Crudeli, D; De Lange, Gj; Slomp, Cp; Erba, E; Corselli, C; Calvert, Se.
High relative concentrations of the lower photic zone nannofossil Florisphaera profunda have been reported in all recent eastern Mediterranean sapropels. In the most recent sapropel (S1), high bulk sediment Sr/Ca ratios occur along with high F. profunda contents toward the base of the unit, exemplified here in four cores from 1.5-3.5 km water depth. Co-occurring biogenic carbonates contain insufficient Sr to account for these high Sr concentrations, and X-ray diffraction and selective leaching show that the high Sr/Ca ratios are due to aragonite, the CaCO3 polymorph that is rarely preserved in deep marine sediments, with similar to1 wt % Sr. The possible sources of this aragonite include ( 1) precipitation with surface ocean production, ( 2) detrital input...
Tipo: Text Palavras-chave: Sapropel; Aragonite; Strontium.
Ano: 2004 URL: https://archimer.ifremer.fr/doc/00229/33975/32412.pdf
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Enhanced regeneration of phosphorus during formation of the most recent eastern Mediterranean sapropel (S1) ArchiMer
Slomp, Cp; Thomson, J; De Lange, Gj.
Phosphorus regeneration and burial fluxes during and after formation of the most recent sapropel Sl were determined for two deep-basin, low-sedimentation sites in the eastern Mediterranean Sea. Organic C/P ratios and burial fluxes indicate enhanced regeneration of P relative to C during deposition of sapropel S1. This is largely due to the enhanced release of P from organic matter during sulfate reduction. Release of P from Fe-bound P also increased, but this was only a relatively minor source of dissolved P. Pore-water HPO42- concentrations remained too low for carbonate fluorapatite formation. An increased burial of biogenic Ca-P (i.e., fish debris) was observed for one site. Estimated benthic fluxes of P during sapropel formation were elevated relative...
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Ano: 2002 URL: https://archimer.ifremer.fr/doc/00223/33410/31854.pdf
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