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Strain-induced crystallization in a carbon-black filled polychloroprene rubber: kinetics and mechanical cycling ArchiMer
Le Gac, Pierre Yves; Albouy, Pierre-antoine; Sotta, Paul.
It is shown in the present paper how the addition of a moderate amount of carbon black filler to a polychloroprene gum modifies the local strain state and alters the ability of the polymer to strain-crystallize. The study combines mechanical and X-ray diffraction performed during classical mechanical cycling and tensile impact tests. It highlights the fact that the strain modification induced by the filler addition is highly inhomogeneous: the crystallization behavior and the local draw ratio state are affected differently. The partial relaxation of the amorphous fraction by the strain-induced crystallization peviously evidenced in the pure gum is still present and should play a protective role. The effect of temperature on the crystallization correlates...
Tipo: Text Palavras-chave: Polychloroprene; Strain-induced crystallization; X-ray.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00488/60003/63239.pdf
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