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New insight into the contributions of thermogenic processes and biogenic sources to the generation of organic compounds in hydrothermal fluids ArchiMer
Konn, Cecile; Testemale, D.; Querellou, Joel; Holm, N. G.; Charlou, Jean-luc.
Experiments on hydrothermal degradation of Pyrococcus abyssi biomass were conducted at elevated pressure (40 MPa) over a 200-450 degrees C temperature range in sapphire reaction cells. Few organic compounds could be detected in the 200 degrees C experiment. This lack was attributed to an incomplete degradation of P. abyssi cells. On the contrary, a wide range of soluble organic molecules were generated at temperatures >= 350 degrees C including toluene, styrene, C-8-C-16 alkyl-benzenes, naphthalene, C-11-C-16 alkyl-naphthalenes, even carbon number C-12-C-18 polycyclic aromatic hydrocarbons, C-15-C-18 alkyl-phenanthrenes and C-8:0-C-16:0 n-carboxylic acids. The effect of time on the final organic composition of the degraded P. abyssi solutions at 350...
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Ano: 2011 URL: http://archimer.ifremer.fr/doc/00023/13416/10475.pdf
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