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Transformation de la phase solide à travers l’estuaire de la Loire en relation avec son environnement chimique et biologique ArchiMer
Thibault De Chanvalon, Aubin.
Before reaching the ocean, riverine particles from the Loire watershed undergo important chemical transformations in the estuary. This study aims to identify and characterize main processes involving iron (and to a lesser extent Al, Mn, PO4 3- and rare earths elements). Suspended particulate matter data show that 15% of their iron is lost through the estuary. Reductive iron dissolution during deposition periods is likely to explain most of this loss. However, estuarine sediments are characterized by high spatial heterogeneity due to macrofaunal activities. To overcome this difficulty, new methodologies of high resolution and two-dimensional analyses and calculation of pore water, sediment and benthic meiofauna were developed. These developments enable to...
Tipo: Text Palavras-chave: Estuaire; Fer; Phosphore; Nitrate; Foraminifère benthique; Diagenèse précoce; Loire; Bioturbation; Estuary; Iron; Phosphorus; Nitrate; Benthic foraminifera; Precocious diagenesis; Loire; Bioturbation.
Ano: 2016 URL: https://archimer.ifremer.fr/doc/00498/60932/64325.pdf
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Two-dimensional ammonium distribution in sediment pore waters using a new colorimetric diffusive equilibration in thin-film technique ArchiMer
Metzger, Edouard; Barbe, Anthony; Cesbron, Florian; Thibault De Chanvalon, Aubin; Jauffrais, Thierry; Jézéquel, Didier; Mouret, Aurélia.
This study presents a new gel based technique to describe the pore water ammonium distribution through the sediment-water interface in two dimensions at a millimeter scale. The technique is an adaptation of the classical colorimetric method based on the Berthelot's reaction. After the thin film of the gel probe was equilibrated by diffusion either in standard solutions or in pore waters, a colorimetric reagent gel was set on the gel probe, allowing development of the characteristic green color. A flatbed scanner and subsequent densitometry image analysis allowed to determine the concentration distribution of ammonium. The gel probe was tested in the laboratory for two media, deionized water and seawater, within the range 0–3000 μM in NH4+. Detection limit...
Tipo: Text Palavras-chave: Biogeochemistry; High-resolution; Porewater; DET; Densitometry.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00474/58557/61112.pdf
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