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Thin molecular films of supramolecular porphyrins Anais da ABC (AABC)
ARAKI,KOITI; LIMA,SIMONE DE SOUZA; WINNISCHOFER,HERBERT.
A relevant series of symmetric supramolecular porphyrins has been obtained by attaching four [Ru II(bipy)2Cl] groups to the pyridyl substituents of meso-tetra(4-pyridyl)porphyrin and its metallated derivatives. These compounds display a rich electrochemistry and versatile catalytic, electrocatalytic and photochemical properties, associated with the ruthenium-bipyridine and the porphyrin complexes. These properties can be transferred to the electrodes by attaching thin molecular films of the compounds, by dip-coating, electrostatic assembly or electropolymerization. In this way, the interesting properties of those supermolecules and supramolecular assemblies can be used to prepare molecular devices and sensors.
Tipo: Info:eu-repo/semantics/article Palavras-chave: Polynuclear porphyrins; Thin molecular films; Chemical sensors.
Ano: 2000 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652000000100003
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Electronic tongue system to evaluate flavor of soybean (Glycine Max (L.) Merrill) genotypes BABT
Zoldan,Sandra Maria; Braga,Guilherme de Souza; Fonseca,Fernando Josepetti; Carrão-Panizzi,Mercedes Concórdia.
An electronic tongue system was tested as a fast and efficient analytical tool for flavor evaluation of soybean genotypes. Grain samples of 25 soybean lines were analyzed using 0.25 g of milled samples added to 100 mL of distilled water and mixing for one minute on a magnetic stirrer. An aliquot (50 mL) from the filtered liquid was used for the analysis on a pre-fixed frequency of 1 kHz and alternate tension of 50 mV. Two analyses were conducted in a complete randomized design with three replicates. Electrical response (capacitance) of eight polymeric chemical sensors used to analyze the soybean lines were submitted to Principal Component Analysis (PCA). In the spatial distribution of the PCA graphic, the lines close to each other were similar, while the...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Electronic tongue system; Chemical sensors; Special soybean grains; Beany flavor; Vegetable types.
Ano: 2014 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-89132014000500797
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