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Trace Element Determinations in Fe-Mn Oxides by High Resolution ICP-MS after Tm Addition ArchiMer
Charles, Claire; Barrat, Jean-alix; Pelleter, Ewan.
In order to propose an optimal analytical procedure specific to ferromanganese (Fe-Mn) oxides, we investigated different modes of data acquisition using inductively coupled plasma mass spectrometry (ICP-MS). The results of trace element and Rare Earth Element (REE) determination in eight Fe-Mn nodules and crusts (FeMn-1, GSMC-1, GSMC-2, GSMC-3, GSPN-2, GSPN-3, NOD-A-1 and NOD-P-1) are presented here. The analytical procedure involves chemical dissolution of the Fe-Mn oxides and addition of a thulium (Tm) spike. The correction of measured values from potential isobaric interferences was investigated using both corrections based on mono-elemental solutions, and data acquisition in the high-resolution mode. The obtained results show that the high-resolution...
Tipo: Text Palavras-chave: ICP-MS; Fe-Mn oxides; Trace elements; Rare earth elements; High-resolution; Tm spike.
Ano: 2021 URL: https://archimer.ifremer.fr/doc/00692/80377/83498.pdf
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