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Briand, Elisabeth; Salmain, Michèle; Compere, Chantal; Pradier, Claire-marie. |
Binary mixtures of 11-mercaptoundecanoic acid (MUA) and other thiols of various lengths and terminal functions were chemisorbed on gold-coated surfaces via S-Au bonds to form mixed self-assembled monolayers (SAMs). Several values of the inole fraction of MUA in the thiol mixtures were tested and the structure and composition of the resulted thin films were characterized by X-ray photoelectron spectroscopy (XPS) and polarization modulation infrared reflection-absorption spectroscopy (PM-IRRAS). The results made it clear that co-adsorption of MUA with thiols of similar chain length led to well-ordered monolayers whereas the co-adsorption of MUA with shorter thiols yielded less crystalline-like thin films, but with more reactive carboxylic acid terminal... |
Tipo: Text |
Palavras-chave: PM IRRAS; Antibody; Protein A; Gold; Self assembled monolayers. |
Ano: 2006 |
URL: http://archimer.ifremer.fr/doc/2006/publication-2222.pdf |
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Mexias,André S.; Berger,Gilles; Gomes,Márcia E.B.; Formoso,Milton L.L.; Dani,Norberto; Frantz,José C.; Bongiolo,Everton M.. |
A geochemical modeling of gold deposition was performed using the EQ3/EQ6 software package using conditions inferred from geological, petrographic, geochemical and fluid inclusion data from the Bloco do Butiá gold mine, Lavras do Sul, RS. Gold in the mine occurs only in the pyrite structure (invisible gold). The pyrite occurs associated with white mica (phengite) in the zone of phyllic alteration. The process of gold deposition showed to be related to temperature and pH decrease. The pH decrease was fundamental to gold deposition by destabilization of sulfur species [Au(HS)2- , HAu(HS)2(0) and Au(HS)0] dissolved in the aqueous solution, being Au(HS)0 the main gold transporting complex. The addition of KCl is hard to accept as cause of gold precipitation... |
Tipo: Info:eu-repo/semantics/article |
Palavras-chave: Geochemical modeling; Gold; Pyrite; Sulfur; Fluid-rock interaction. |
Ano: 2005 |
URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652005000400010 |
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Madrigal-Arias,Jorge Enrique; Argumedo-Delira,Rosalba; Alarcón,Alejandro; Mendoza-López,Ma. Remedios; García-Barradas,Oscar; Cruz-Sánchez,Jesús Samuel; Ferrera-Cerrato,Ronald; Jiménez-Fernández,Maribel. |
In an effort to develop alternate techniques to recover metals from waste electrical and electronic equipment (WEEE), this research evaluated the bioleaching efficiency of gold (Au), copper (Cu) and nickel (Ni) by two strains of Aspergillus niger in the presence of gold-plated finger integrated circuits found in computer motherboards (GFICMs) and cellular phone printed circuit boards (PCBs). These three metals were analyzed for their commercial value and their diverse applications in the industry. Au-bioleaching ranged from 42 to 1% for Aspergillus niger strain MXPE6; with the combination of Aspergillus niger MXPE6 + Aspergillus niger MX7, the Au-bioleaching was 87 and 28% for PCBs and GFICMs, respectively. In contrast, the bioleaching of Cu by Aspergillus... |
Tipo: Info:eu-repo/semantics/article |
Palavras-chave: Bioleaching; PCBs; Aspergillus; Gold; WEEE. |
Ano: 2015 |
URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1517-83822015000300707 |
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