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| Charles, Claire; Barrat, Jean-alix; Pelleter, Ewan. |
| In order to propose an optimal analytical procedure specific to ferromanganese (Fe-Mn) oxides, we investigated different modes of data acquisition using inductively coupled plasma mass spectrometry (ICP-MS). The results of trace element and Rare Earth Element (REE) determination in eight Fe-Mn nodules and crusts (FeMn-1, GSMC-1, GSMC-2, GSMC-3, GSPN-2, GSPN-3, NOD-A-1 and NOD-P-1) are presented here. The analytical procedure involves chemical dissolution of the Fe-Mn oxides and addition of a thulium (Tm) spike. The correction of measured values from potential isobaric interferences was investigated using both corrections based on mono-elemental solutions, and data acquisition in the high-resolution mode. The obtained results show that the high-resolution... |
| Tipo: Text |
Palavras-chave: ICP-MS; Fe-Mn oxides; Trace elements; Rare earth elements; High-resolution; Tm spike. |
| Ano: 2021 |
URL: https://archimer.ifremer.fr/doc/00692/80377/83498.pdf |
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| Metzger, Edouard; Barbe, Anthony; Cesbron, Florian; Thibault De Chanvalon, Aubin; Jauffrais, Thierry; Jézéquel, Didier; Mouret, Aurélia. |
| This study presents a new gel based technique to describe the pore water ammonium distribution through the sediment-water interface in two dimensions at a millimeter scale. The technique is an adaptation of the classical colorimetric method based on the Berthelot's reaction. After the thin film of the gel probe was equilibrated by diffusion either in standard solutions or in pore waters, a colorimetric reagent gel was set on the gel probe, allowing development of the characteristic green color. A flatbed scanner and subsequent densitometry image analysis allowed to determine the concentration distribution of ammonium. The gel probe was tested in the laboratory for two media, deionized water and seawater, within the range 0–3000 μM in NH4+. Detection limit... |
| Tipo: Text |
Palavras-chave: Biogeochemistry; High-resolution; Porewater; DET; Densitometry. |
| Ano: 2019 |
URL: https://archimer.ifremer.fr/doc/00474/58557/61112.pdf |
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