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Iron sources and dissolved-particulate interactions in the seawater of the Western Equatorial Pacific, iron isotope perspectives ArchiMer
Labatut, M.; Lacan, F.; Pradoux, C.; Chmeleff, J.; Radic, A.; Murray, J. W.; Poitrasson, F.; Johansen, A. M.; Thil, F..
This work presents iron isotope data in the western equatorial Pacific. Marine aerosols and top core margin sediments display a slightly heavy Fe isotopic composition (Fe-56) of 0.330.11 (2SD) and 0.140.07, respectively. Samples reflecting the influence of Papua New Guinea runoff (Sepik River and Rabaul volcano water) are characterized by crustal values. In seawater, Fe is mainly supplied in the particulate form and is found with a Fe-56 between -0.49 and 0.34 +/- 0.07 parts per thousand. The particulate Fe seems to be brought mainly by runoff and transported across continental shelves and slopes. Aerosols are suspected to enrich the surface Vitiaz Strait waters, while hydrothermal activity likely enriched New Ireland waters. Dissolved Fe isotopic ratios...
Tipo: Text Palavras-chave: Iron isotopes; Particles; Equatorial Pacific; Papua New Guinea; Seawater; GEOTRACES.
Ano: 2014 URL: https://archimer.ifremer.fr/doc/00290/40074/39162.pdf
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Origin of red beds in the Paleoproterozoic Franceville Basin, Gabon, and implications for sandstone-hosted uranium mineralization ArchiMer
Bankole, Olabode M.; El Albani, Abderrazak; Meunier, Alain; Rouxel, Olivier; Gauthier-lafaye, Francois; Bekker, Andrey.
Red beds are extensively used as evidence for an oxygenated atmosphere in the Paleoproterozoic. Red beds in the unmetamorphosed, ca. 2.15 Ga FA Formation of the Franceville Basin, Gabon were geochemically, petrographically, and mineralogically characterized to constrain the process of their formation and their relationship to atmospheric oxygenation in the early Paleoproterozoic. Petrographic observations indicate that ferric oxides are dispersed in clay filling intergranular pores and along platy cleavage in altered phyllosilicates. Grain-coating hematite is generally rare to absent in most samples suggesting hematite precipitation after sediment deposition and during burial diagenesis. Textures and geochemical data suggest that iron was likely sourced...
Tipo: Text Palavras-chave: Red beds; Atmospheric oxygenation; Diagenesis; Iron isotopes; Franceville Basin; Oldest sandstone-type U deposit.
Ano: 2016 URL: http://archimer.ifremer.fr/doc/00358/46966/48278.pdf
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Comparing orthomagmatic and hydrothermal mineralization models for komatiite-hosted nickel deposits in Zimbabwe using multiple-sulfur, iron, and nickel isotope data ArchiMer
Hofmann, Axel; Bekker, Andrey; Dirks, Paul; Gueguen, Bleuenn; Rumble, Doug; Rouxel, Olivier.
Trojan and Shangani mines are low-grade (<0.8 % Ni), komatiite-hosted nickel sulfide deposits associated with ca. 2.7 Ga volcano-sedimentary sequences of the Zimbabwe craton. At both mines, nickel sulfide mineralization is present in strongly deformed serpentinite bodies that are enveloped by a complex network of highly sheared, silicified, and sulfide-bearing metasedimentary rocks. Strong, polyphase structural–metamorphic–metasomatic overprints in both the Trojan and Shangani deposits make it difficult to ascertain if sulfide mineralization was derived from orthomagmatic or hydrothermal processes, or by a combination of both. Multiple S, Fe, and Ni isotope analyses were applied to test these competing models. Massive ores at Shangani Mine show...
Tipo: Text Palavras-chave: Komatiite-hosted nickel deposit; Zimbabwe craton; Archean; Sulfur isotopes; Iron isotopes; Nickel isotopes.
Ano: 2014 URL: http://archimer.ifremer.fr/doc/00171/28207/26508.pdf
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Iron isotopes reveal distinct dissolved iron sources and pathways in the intermediate versus deep Southern Ocean ArchiMer
Abadie, Cyril; Lacan, Francois; Radic, Amandine; Pradoux, Catherine; Poitrasson, Franck.
As an essential micronutrient, iron plays a key role in oceanic biogeochemistry. It is therefore linked to the global carbon cycle and climate. Here, we report a dissolved iron (DFe) isotope section in the South Atlantic and Southern Ocean. Throughout the section, a striking DFe isotope minimum (light iron) is observed at intermediate depths (200–1,300 m), contrasting with heavier isotopic composition in deep waters. This unambiguously demonstrates distinct DFe sources and processes dominating the iron cycle in the intermediate and deep layers, a feature impossible to see with only iron concentration data largely used thus far in chemical oceanography. At intermediate depths, the data suggest that the dominant DFe sources are linked to organic matter...
Tipo: Text Palavras-chave: Iron isotopes; GEOTRACES; South Atlantic; Southern Ocean; Remineralization.
Ano: 2017 URL: https://archimer.ifremer.fr/doc/00367/47864/47859.pdf
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