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Thermodynamic properties of water desorption of forage turnip seeds Agronomy
Sousa, Kelly Aparecida; Resende, Osvaldo; Goneli, André Luis Duarte; Smaniotto, Thaís Adriana de Souza; Oliveira, Daniel Emanuel Cabral de.
The purpose of this study was to determine the thermodynamic properties of the process of water sorption in forage turnip  seeds. The equilibrium moisture content of forage turnip  seeds was determined by the gravimetric-dynamic method for different values of temperature and water activity. According to the results, increasing the moisture content increases the energy required for the evaporation of water in forage turnip seeds, and the values of integral isosteric heat of desorption, within the moisture content range of 3.33 to 11.30 (% d.b.), varies from 4,222.70 to 2,870.34 kJ kg-1. With the elevation in the equilibrium moisture content, there is an increase in differential entropy and Gibbs free energy, which has positive values, demonstrating...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Ciências Ágrarias; Armazenamento de produtos agrícolas hygroscopic equilibrium; Isosteric heat; Gibbs free energy; Compensation theory Ciências Ágrarias; Armazenamento de produtos agrícolas.
Ano: 2014 URL: http://periodicos.uem.br/ojs/index.php/ActaSciAgron/article/view/19333
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Kinetic modeling of water sorption by roasted and ground coffee Agronomy
Baptestini, Fernanda Machado; Corrêa, Paulo Cesar; Oliveira, Gabriel Henrique Horta de; Cecon, Paulo Roberto; Soares, Nilda de Fátima Ferreira.
The objective of this study was to model the kinetics of water sorption in roasted and ground coffee. Crude Arabica coffee beans with an initial moisture content of 0.1234 kgwkgdm-1 were used. These beans were roasted to a medium roast level (SCCA # 55) and ground at three particle sizes: coarse (1.19 mm), medium (0.84 mm) and fine (0.59 mm). To obtain the water sorption isotherms and the isosteric heat, different conditions of temperature and relative humidity were analyzed using the dynamic method at 25ºC (0.50, 0.60, 0.70, and 0.80 of RH) and 30°C (0.30, 0.40, 0.50, 0.60, 0.70, and 0.80 of RH) and using the static method at 25ºC (0.332 and 0.438 of RH). The GAB model best represented the hygroscopic equilibrium of roasted coffee at every particle size....
Tipo: Info:eu-repo/semantics/article Palavras-chave: Particle size; Specific surface; Isosteric heat.
Ano: 2017 URL: http://periodicos.uem.br/ojs/index.php/ActaSciAgron/article/view/32576
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Moisture sorption isotherms and thermodynamic properties of Asteriscus graveolens leaves CIGR Journal
Saad, Amel; Touati, Boumediene; Draoui, Belkacem; Tabti, Boufeldja; Abdenebi, Asma; Mir, Krima.
Asteriscus graveolens is a medicinal and aromatic plant which has been used to treat several diseases.Moisture equilibrium data of the plant leaves were determined by using the gravimetric static method at 30°C, 40°C, and 50°C for water activity (
Tipo: Info:eu-repo/semantics/article Palavras-chave: Moisture sorption; Isotherm; Asteriscus graveolens; Isosteric heat; Modelling.
Ano: 2016 URL: http://www.cigrjournal.org/index.php/Ejounral/article/view/3585
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Effect of moisture sorption hysteresis on thermodynamic properties of two millet varieties CIGR Journal
AVIARA, NDUBISI A.; Ojediran, John O.; Marwan, Sa'id U.; Raji, Abdulganiy O..
Application of reversible thermodynamic principles to gain fundamental understanding of food–water interactions in foods has met with limited success due to the presence of moisture sorption hysteresis which is a manifestation of irreversibility. This study was aimed at understanding the nature and extent of influence of hysteresis on thermodynamic properties of two millet varieties namely EX-BORNO and SOSAT C88. Moisture sorption data (adsorption and desorption) in the water activity and temperature ranges of 0.07 – 0.98 and 30°C – 70°C, respectively were used. Ratio of latent heat of moisture sorption to the latent heat of pure water was determined using Clausius-Clapeyron equation. Effect of moisture content on ratio of latent heat of sorption to latent...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Processing and storage Engineering EX-BORNO; SOSAT C88; Latent heat of moisture sorption; Spreading pressure; Net integral enthalpy and entropy; Isosteric heat; Differential entropy; Enthalpy-entropy compensation.
Ano: 2016 URL: http://www.cigrjournal.org/index.php/Ejounral/article/view/3531
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Modeling Isosteric Heat of Soya Bean for Desorption Energy Estimation Using Neural Network Approach Chilean J. Agric. Res.
Amiri Chayjan,Reza; Esna-Ashari,Mahmood.
Sorption isotherm of soya bean (Glycine max (L.) Merr.) was obtained by the dynamic experimental method. Artificial Neural Networks (ANNs) were used for modeling soya bean equilibrium moisture content (EMC). Thermodynamic equations and trained ANN for prediction of two thermodynamic properties of net isosteric heat and entropy of soya bean were utilized. The ANN models were better compared with mathematical models. In this study, the isosteric heat and entropy of sorption of soya bean were separately predicted by two power models as a EMC function. Predictive power of the models was high (R² ≈ 0.99). At the moisture content above 11% (dry basis, db), isosteric heat and entropy of sorption of soya bean were smoothly decreased, while they were...
Tipo: Journal article Palavras-chave: Back propagation; Entropy; Isosteric heat; Sorption isotherm; Soya bean.
Ano: 2010 URL: http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0718-58392010000400012
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Moisture sorption isotherms of sunflower seeds: Thermodynamic analysis Ciência e Agrotecnologia
Campos,Renata Cássia; Correa,Paulo César; Zaidan,Iasmine Ramos; Zaidan,Úrsula Ramos; Leite,Rildo Araújo.
ABSTRACT The study of the thermodynamic properties provides the knowledge of the sorbent affinity by the water and the spontaneity of the sorption process, important to design drying equipment and to predict hygroscopic behavior during storage. This work aimed to determine and evaluate isotherms of hygroscopic equilibrium and thermodynamic properties for different equilibrium conditions (water contents and temperatures) in sunflower seeds, using the indirect static method. Sunflower seeds with initial water content of 0.164 (decimal, dry basis - d.b.) were used. Fifteen mathematical models were tested for hygroscopic equilibrium modeling, and the Smith model presented the best fit. It was verified that the thermodynamic properties were influenced by the...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Hygroscopic equilibrium; Isosteric heat; Enthalpy; Entropy; Gibbs free energy..
Ano: 2019 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1413-70542019000100227
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Moisture sorption isotherms of fresh and blanched pumpkin (Cucurbita moschata) Ciênc. Tecnol. Aliment.
Molina Filho,Lucídio; Gonçalves,Ana Karla Rebes; Mauro,Maria Aparecida; Frascareli,Elen Cristina.
Moisture desorption isotherms of fresh and heat blanched pumpkins (Cucurbita moschata) were determined at three temperatures (30, 50 and 70 °C), using the standard, static-gravimetric method. The GAB, Oswin, BET, Halsey, and Henderson models were tested and, with the exception of the Henderson model, showed satisfactory fits to the experimental data. The GAB model was used to analyze the fitting ability to describe the isotherm type. The shape of the desorption isotherms of fresh and blanched pumpkin at 30 and 50 °C was intermediate to types II and III, and at 70 °C it was of type II for the blanched pumpkin and close to type II for the fresh sample. The influence of blanching on the decrease in equilibrium moisture was very small compared to the fresh...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Blanching; Pumpkin; Desorption isotherms; Isosteric heat; GAB model.
Ano: 2011 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0101-20612011000300025
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MOISTURE SORPTION ISOTHERMS OF QUINOA SEEDS: THERMODYNAMIC ANALYSIS REA
Bustos-Vanegas,Jaime D.; Corrêa,Paulo C.; Zeymer,Juliana S.; Baptestini,Fernanda M.; Campos,Renata C..
ABSTRACT The present research aimed to study the water sorption behavior of quinoa seeds analyzing the hysteresis phenomenon and determining thermodynamic properties. Static gravimetric technique was used to obtain the equilibrium moisture content of quinoa seeds in different temperature conditions (15, 25, 35 e 50 °C) and relative humidity (between 11 and 96%). Equilibrium moisture content data were adjusted by eight mathematical models and the Modified Halsey model was the best one to describe the water sorption phenomena of quinoa seeds. Hygroscopic equilibrium moisture content of quinoa seeds is directly proportional to the water activity and decreases with increasing temperature. The hysteresis phenomena were observed throughout the range of water...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Entropy; Gibbs energy; Hysteresis; Isosteric heat; Mathematical modeling.
Ano: 2018 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-69162018000600941
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Hygroscopicity of ‘sucupira-branca’ (Pterodon emarginatus Vogel) fruits AGRIAMBI
Oliveira,Daniel E. C. de; Resende,Osvaldo; Costa,Lílian M.; Silva,Glicélia P.; Sales,Juliana de F..
ABSTRACT ‘Sucupira-branca’ (Pterodon emarginatus Vogel) is a tree from ‘Cerrado’ and stands out mainly for its pharmacological properties; however, there are no technological information about its post-harvest operations. Thus, the aim of this study was to determine the sorption isotherms of ‘sucupira-branca’ fruits for different air conditions and obtain the values of desorption isosteric heat, depending on the equilibrium moisture content of the product. The equilibrium moisture content of ‘sucupira-branca’ fruits was determined by dynamic method for temperatures of 25, 30, 35 and 40 °C and water activities for each temperature between 0.270 and 0.775. The models Chung-Pfost, Copace, Modified Halsey, Oswin Modified and Sigma Copace obtained high...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Equilibrium moisture content; Isotherms; Water activity; Isosteric heat; Copace.
Ano: 2017 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1415-43662017000400285
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Post-harvest of parsley leaves (Petroselinum crispum): Mathematical modelling of drying and sorption processes AGRIAMBI
Corrêa Filho,Luiz C.; Martinazzo,Ana P.; Teodoro,Carlos E. de S.; Andrade,Ednilton T. de.
ABSTRACT Parsley is a species of wide production and trade in Brazil due to its high consumption as a condiment, fresh or dried. In the development of equipment used for drying, it is important to simulate and obtain theoretical information about the behavior of water loss for each product. Given the increasing use and potential commercialization of condimental plants, the objective of this work was to determine the isosteric heat of parsley leaves and fit mathematical models to the experimental data obtained in drying and desorption processes. The modified GAB and Midilli models were the most appropriate to describe the desorption isotherms and drying curves, respectively, for the studied temperatures. The isosteric heat varied from 3394.6 to 2830.0 kJ...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Spice plant; Processing; Isosteric heat.
Ano: 2018 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1415-43662018000200131
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Isotherms and isostatic heat of foam-mat dried yellow mombin pulp AGRIAMBI
Cavalcante,Maisa D.; Plácido,Geovana R.; Oliveira,Daniel E. C. de; Freitas,Bheatriz S. M. de; Cagnin,Caroline; Oliveira,Déborah de S..
ABSTRACT Yellow mombin has high nutritional value but is very perishable. Foam mat drying is a method that has been widely used to preserve liquid and semi-solid powdered foods. In this context, the aim of this study was to determine desorption isotherms and isosteric heat of yellow mombin (Spondias mombin L.) foam for different conditions of temperature and water activity. Powdered yellow mombin pulp was obtained by drying in forced-air oven regulated to 60 ° C. The indirect static method was used to determine the isotherms and isosteric heat, whereas water activity (aw) was determined using the Hygropalm-HP23AW-A analyzer. A B.O.D. incubator, set at 10, 20, 30 and 40 °C, was used to control the temperature, and the water activity for each temperature was...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Water activity; Isosteric heat; Hygroscopicity; Mathematical modeling; Spondias mombin L..
Ano: 2018 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1415-43662018000600436
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Desorption isotherms of flaxseeds (Linum usitatissimum L.) and thermodynamic parameters of the process Rev. Ciênc. Agron.
Valente,Maria da Conceição da Costa; Nascimento,Rafael Alves do; Santana,Elza Brandão; Faria,Lênio José Guerreiro de; Costa,Cristiane Maria Leal.
ABSTRACT Sorption isotherms of flaxseeds were determined by static gravimetric method at temperatures 40, 60, and 80 ºC, over a relative moisture range of 10-95%. Six mathematical models were applied to analyze the experimental data. The modified GAB model showed the best fitting to the experimental data. The isosteric heat and differential entropy were determined by applying the Clausius-Clapeyron and Gibbs-Helmholtz equations, respectively. The isosteric heat and the entropy of desorption isotherm presented similar behavior, with a sharp change of 10% in the equilibrium moisture content. The enthalpy-entropy compensation theory was applied to the isotherms, indicating that they are enthalpy-controlled.
Tipo: Info:eu-repo/semantics/article Palavras-chave: Equilibrium moisture content; Drying; Isosteric heat.
Ano: 2020 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1806-66902020000200401
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