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Distribution et role des composes soufres reduits volatils sur la speciation metallique ArchiMer
Cozic, Amandine.
A sensitive, precise and rapid analytical method was elaborated to measure simultaneously 5 volatile reduced sulfur compounds (VRSC) ; hydrogen sulfide (H2S), carbonyl sulfide (OCS), methane thiol (MeSH), dimethyl sulfide (DMS), dimethyl disulfide (DMDS). The study of VRSC in the Bay of Quiberon highlights seasonal and interannual variations of concentrations in epibenthic zone. H2S analyzed near the sediment water interface (anoxic microzones), is more elevated in summer. The OCS distribution is consistent with a predominant photodegradation in winter and a sedimentary source in summer. The variations of MeSH, DMS and DMDS are correlated with the Dinophyceae abundance. In the Seine estuary, the absence of volatile H2S in the up estuary is explained by the...
Tipo: Text Palavras-chave: Phytoplankton; Metal speciation; DMS; Sulfur; Phytoplancton; Spéciation métallique; DMS; Soufre.
Ano: 2007 URL: http://archimer.ifremer.fr/doc/2007/these-2687.pdf
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