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Sawdust Derivative for Environmental Application: Chemistry, Functionalization and Removal of textile dye from aqueous solution Anais da ABC (AABC)
PINTO,THAIS F.; BEZERRA,CÍCERO W.B.; SILVA,DOMINGOS S.A.; SILVA FILHO,EDSON C. DA; VIEIRA,ADRIANA P.; AIROLDI,CLAUDIO; MELO,JÚLIO C.P. DE; SILVA,HILDO A.S.; SANTANA,SIRLANE A.A..
ABSTRACT The adsorption of Violet Remazol 5R (VR 5) on wood sawdust modified with succinic anhydride (SSA) as a function of contact time, pH, and initial dye concentrations was investigated using a batch technique under ambient conditions. The SSA obtained was confirmed by IR spectroscopy, thermogravimetry and 13C NMR, and degrees of substitution (DS) were calculated. A study on the effect of the pH on the adsorption of VR 5 showed that the optimum pH was 2.0. The interactions were assayed with respect to the pseudo-first-order and pseudo-second-order kinetic models, and were found to follow closely the pseudo-second-order. The isotherm was adjusted to the Langmuir, the Freundlich and the Temkin sorption models. SSA is a promising material for the removal...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Wood sawdust; Adsorption; Textile dye; Succinic anhydride.
Ano: 2016 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652016000401212
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Synthesis and physicochemical characterization of chemically modified chitosan by succinic anhydride BABT
Mello,Karine Gargioni Pereira Correa de; Bernusso,Leandra de Cássia; Pitombo,Ronaldo Nogueira de Moraes; Polakiewicz,Bronislaw.
The N-succinil-chitosan is a chemically modified derivative of the biopolymer chitosan. The succinic anhydride attached to the free amino groups presented along the chitosan's polymer chain imparts to the molecule different physicochemical properties not exhibited before the modification. These chemical modifications enhance chitosan's solubility in slightly acid, neutral and alkaline media. These properties are related to the long alkyl chains attached to hydrophilic parts. In this case the hydrophilic part of D-glucosamine promotes stronger interactions with the water molecules, and consequently, enhances the solubility of the chitosan polymer. Non-modified free chitosan is soluble only in acidic medium (pH < 5.5). These modifications made possible...
Tipo: Info:eu-repo/semantics/article Palavras-chave: N-succinil-chitosan; Succinic anhydride; Biopolymer; Solubility.
Ano: 2006 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-89132006000500017
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